A new methanol solvate and Hirshfeld analysis of π-stacking in 2,3,6,7,10,11-hexahydroxytriphenylene solvates
Artikel i vetenskaplig tidskrift, 2013

The structure of 2,3,6,7,10,11-hexahydroxytriphenylene (hhtp) methanol monosolvate, C18H12O6•CH3OH, has triclinic symmetry (space group P1). The compound has a threedimensional layered network structure formed by intermolecular hydrogen bonding. Structure analysis with Hirshfeld surfaces is shown to be a sensitive method for comparing π -stacking effects in the five known solvates of hhtp. The title structure shows slightly weaker π -stacking than the dihydrate, but stronger π -stacking than the other three solvates.

crystallography

Författare

Anirban Karmakar

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

A.E. Platero-Prats

Stockholms universitet

Lars Öhrström

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Acta Crystallographica Section C: Crystal Structure Communications

0108-2701 (ISSN) 1600-5759 (eISSN)

Vol. C69 251-254

Ämneskategorier

Oorganisk kemi

Annan kemi

Organisk kemi

Styrkeområden

Nanovetenskap och nanoteknik

Materialvetenskap

Fundament

Grundläggande vetenskaper

DOI

10.1107/S0108270113001893