Crystal structure of Eu(CyMe4-BTBP)(2)kappa O-2,O '-(NO3) (NO3)(2)center dot n-C8H17OH and its structure in 1-octanol solution
Artikel i vetenskaplig tidskrift, 2013

The structure of the [Eu(CyMe4-BTBP)(2)(NO3)(n)]((3-n)+) complex in 1-octanol solution and solid state has been determined by EXAFS and X-ray crystallography. The crystal structure shows that 1-octanol binds only to the europium(III)-coordinated BTBP molecules through weak van der Waals forces, making it the first indication of the role of the extraction solvent.

Författare

D. Lundberg

Sveriges lantbruksuniversitet (SLU)

I. Persson

Sveriges lantbruksuniversitet (SLU)

Christian Ekberg

Chalmers, Kemi- och bioteknik, Kärnkemi

Dalton Transactions

1477-9226 (ISSN) 1477-9234 (eISSN)

Vol. 42 3767-3770

Ämneskategorier

Kemi

DOI

10.1039/c2dt32317f