2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))
Artikel i vetenskaplig tidskrift, 1996

Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.

X-RAY STRUCTURE

LAWESSONS REAGENT

Författare

Mark Foreman

Institutionen för kärnkemi

J.Derek Woollins

Alex.M.Z. Slawin

Journal of the Chemical Society. Dalton Transactions

1472-7773 (ISSN)

18 3653-3657

Ämneskategorier

Oorganisk kemi

Kemi

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2018-01-30