High performance all-polymer photodetector comprising a donor-Acceptor-Acceptor structured indacenodithiophene-bithieno[3,4-c] pyrroletetrone copolymer
Artikel i vetenskaplig tidskrift, 2018

The synthesis of an acceptor polymer PIDT-2TPD, comprising indacenodithiophene (IDT) as the electron-rich unit and an interconnected bithieno[3,4-c]pyrrole-4,4′,6,6′-Tetrone (2TPD) as the electron-deficient unit, and its application for all-polymer photodetectors is reported. The optical, electrochemical, charge transport, and device properties of a blend of poly(3-hexylthiophene) and PIDT-2TPD are studied. The blend shows strong complementary absorption and balanced electron and hole mobility, which are desired properties for a photoactive layer. The device exhibits dark current density in the order of 10 -5 mA/cm 2 , external quantum efficiency broadly above 30%, and nearly planar detectivity over the entire visible spectral range (maximum of 1.1 × 10 12 Jones at 610 nm) under-5 V bias. These results indicate that PIDT-2TPD is a highly functional new type of acceptor and further motivate the use of 2TPD as a building block for other n-Type materials.

Författare

Petri Henrik Murto

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

Zewdneh Genene

Addis Ababa University

Ambo University

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Cindy Montenegro Benavides

Friedrich-Alexander-Universität Erlangen Nurnberg (FAU)

Siemens

Xiaofeng Xu

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

A. Sharma

Universite de Bordeaux

Flinders University

Xun Pan

Flinders University

Oliver Schmidt

Siemens

Christoph J. Brabec

Das Bayerische Zentrum fur Angewandte Energieforschung e.V.

Friedrich-Alexander-Universität Erlangen Nurnberg (FAU)

Mats Andersson

Flinders University

W. Mammo

Addis Ababa University

Sandro F. Tedde

Siemens

Ergang Wang

Ergang Wang Group

ACS Macro Letters

2161-1653 (eISSN)

Vol. 7 395-400

Ämneskategorier

Polymerkemi

Materialkemi

Den kondenserade materiens fysik

DOI

10.1021/acsmacrolett.8b00009