Conformational chiral polymorphism in cis-bis-triphenylphosphine complexes of transition metals
Artikel i vetenskaplig tidskrift, 2018

The structure of cis-[Mo(CO)4(PPh3)2] 1 was determined by F. A. Cotton, D. J. Darensbourg, S. Klein and B. W. S. Kolthammer, Inorg. Chem., 1982, 21, 1651-1655, with the space group P1. A second polymorph 2 is reported here, with the space group P21/c. The compounds differ in the interactions between the conformational chiral triphenylphosphine groups. In 1, there is π-π stacking between adjacent phenyl groups, whereas in 2, there are σ-π interactions instead. A search of the Cambridge Structural Database reveals that this is a relatively frequent occurrence in cis-bis-triphenylphosphine complexes and the phenomenon can be analysed by means of the C(ipso)-P-M-P torsion angles. The majority of compounds fall in the π-π stacking data area with torsion angles of 10-15° and 55-60°; however, for octahedrally coordinated metals, the optimum is a σ-π interaction at 40°/40°. This corresponds well to the values in 2: 46°/40°, but for 1, we instead find the torsion angles to be 11°/18°. There is indeed a small occurrence of these values as well in the data, and it appears that for 1, this conformation is stabilised by weak COH-C hydrogen bonds. Density functional theory (DFT) calculations indicate that 1 is the more stable polymorph by 72 kJ mol−1but that the strain of the complexes (the difference between a relaxed molecule in the respective conformation and the structure in the crystal) is larger for 1 than for 2, further indicating that a special intermolecular interaction is responsible for the stability of this polymorph. In both polymorphs, the triphenylphosphines have the same conformational chirality, consistent with single-molecule calculations that predict racemic conformations to be substantially higher in energy for both σ-π interactions (+17 kJ mol−1) and π-π stacking (+30 kJ mol−1).

Författare

Never Tshabang

University of Botswana

Gaone P. Makgatle

University of Botswana

S. A. Bourne

University of Cape Town

Nina Kann

Chalmers, Kemi och kemiteknik, Kemi och biokemi, Fysikalisk kemi

Jack D. Evans

Institut de Recherche de Chimie Paris

Technische Universität Dresden

François Xavier Coudert

Institut de Recherche de Chimie Paris

Lars Öhrström

Chalmers, Kemi och kemiteknik, Kemi och biokemi

CrystEngComm

1466-8033 (ISSN)

Vol. 20 35 5137-5142

Ämneskategorier

Oorganisk kemi

Teoretisk kemi

DOI

10.1039/C8CE00337H

Mer information

Senast uppdaterat

2018-10-30