Solar Energy Storage by Molecular Norbornadiene–Quadricyclane Photoswitches: Polymer Film Devices
Artikel i vetenskaplig tidskrift, 2019

Devices that can capture and convert sunlight into stored chemical energy are attractive candidates for future energy technologies. A general challenge is to combine efficient solar energy capture with high energy densities and energy storage time into a processable composite for device application. Here, norbornadiene (NBD)–quadricyclane (QC) molecular photoswitches are embedded into polymer matrices, with possible applications in energy storing coatings. The NBD–QC photoswitches that are capable of absorbing sunlight with estimated solar energy storage efficiencies of up to 3.8% combined with attractive energy storage densities of up to 0.48 MJ kg −1 . The combination of donor and acceptor units leads to an improved solar spectrum match with an onset of absorption of up to 529 nm and a lifetime (t 1/2 ) of up to 10 months. The NBD–QC systems with properties matched to a daily energy storage cycle are further investigated in the solid state by embedding the molecules into a series of polymer matrices revealing that polystyrene is the preferred choice of matrix. These polymer devices, which can absorb sunlight and over a daily cycle release the energy as heat, are investigated for their cyclability, showing multicycle reusability with limited degradation that might allow them to be applied as window laminates.

solid state materials

heat release

solar energy storage

solar thermal

Författare

Anne U. Petersen

Chalmers, Kemi och kemiteknik

Anna Isabel Hofmann

Chalmers, Kemi och kemiteknik

Méritxell Fillols

Chalmers, Kemi och kemiteknik

Mads Mansø

Köpenhamns universitet

Martyn Jevric

Chalmers, Kemi och kemiteknik

Zhihang Wang

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Kasper Moth-Poulsen Group

Christopher Sumby

University of Adelaide

Christian Müller

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Christian Müller Group

Kasper Moth-Poulsen

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Kasper Moth-Poulsen Group

Advanced Science

2198-3844 (ISSN)

1900367

Ämneskategorier

Annan naturresursteknik

Teoretisk kemi

Energisystem

DOI

10.1002/advs.201900367

Mer information

Senast uppdaterat

2019-07-15