All-Organic Textile Thermoelectrics with Carbon-Nanotube-Coated n-Type Yarns
Artikel i vetenskaplig tidskrift, 2018

Thermoelectric textiles that are able to generate electricity from heat gradients may find use as power sources for a wide range of miniature wearable electronics. To realize such thermoelectric textiles, both p- and n-type yarns are needed. The realization of air-stable and flexible n-type yarns, i.e., conducting yarns where electrons are the majority charge carriers, presents a considerable challenge due to the scarcity of air-stable n-doped organic materials. Here, we realize such n-type yarns by coating commercial sewing threads with a nanocomposite of multiwalled carbon nanotubes (MWNTs) and poly(N-vinylpyrrolidone) (PVP). Our n-type yarns have a bulk conductivity of 1 S cm -1 and a Seebeck coefficient of -14 μV K -1 , which is stable for several months at ambient conditions. We combine our coated n-type yarns with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) dyed silk yarns, constituting the p-type component, to realize a textile thermoelectric module with 38 n/p elements, which are capable of producing an open-circuit voltage of 143 mV when exposed to a temperature gradient of 116 °C and a maximum power output of 7.1 nW at a temperature gradient of 80 °C.

n-type conducting yarn

organic thermoelectrics

carbon nanotubes

electronic textile

polymer nanocomposite

Författare

Jason Ryan

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

Anja Lund

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Anna Isabel Hofmann

Chalmers, Kemi och kemiteknik

Renee Kroon

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Christian Müller Group

Ruben Sarabia-Riquelme

University of Kentucky

M. C. Weisenberger

University of Kentucky

Christian Müller

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Christian Müller Group

ACS Applied Energy Materials

25740962 (eISSN)

Vol. 1 6 2934-2941

Woven and 3D-Printed Thermoelectric Textiles (ThermoTex)

Europeiska forskningsrådet (ERC), 2015-06-01 -- 2020-06-30.

Ämneskategorier

Bearbetnings-, yt- och fogningsteknik

Materialkemi

Den kondenserade materiens fysik

DOI

10.1021/acsaem.8b00617

Mer information

Senast uppdaterat

2019-06-24