Ionic liquid based battery electrolytes using lithium and sodium pseudo-delocalized pyridinium anion salts
Artikel i vetenskaplig tidskrift, 2019

The electrolyte salt plays an important role for the overall performance and safety of lithium- and sodiumion batteries (LIBs and SIBs, respectively). Here, two new lithium and sodium pseudo-delocalized pyridinium anion based salts were used to prepare ionic liquid (IL) based electrolytes. The Li and Na salts of the 1-methylpyridinum 2,6-dicarboxylate anion (MM26py) were synthesized and dissolved in an IL matrix (Pyr14TFSI) – hence creating mixed anion electrolytes. The obtained electrolytes are stable up to 150 and 200 1C and show ion conductivities of 2.8 and 3.2 mS cm1 at room temperature, for the LIB and SIB electrolytes, respectively. A competitive effect between the MM26py and the TFSI anions to coordinate the alkali metal cations is observed. Finally, the electrochemical stability windows of 2.3 and 2.5 V, respectively, confirm that these electrolytes can be used practically in medium-voltage LIBs and SIBs.

Författare

Elham Hosseini Bab Anari

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Kasper Moth-Poulsen Group

Adriana Navarro Suárez

Chalmers, Fysik, Kondenserade materiens fysik

Kasper Moth-Poulsen

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Kasper Moth-Poulsen Group

Patrik Johansson

Chalmers, Fysik, Kondenserade materiens fysik

Physical Chemistry Chemical Physics

1463-9076 (ISSN) 1463-9084 (eISSN)

Vol. 21 18393-18399

Säkrare energilagerlösningar med fluorfria elektrolyter

Energimyndigheten, 2013-12-01 -- 2015-12-31.

Ämneskategorier

Materialteknik

Fysikalisk kemi

Annan teknik

Kemiteknik

Atom- och molekylfysik och optik

Annan naturvetenskap

Styrkeområden

Energi

Materialvetenskap

DOI

10.1039/c9cp03445e

Mer information

Skapat

2019-10-08