The CO2/CO3 2− chemistry of the NaOH(aq) model system applicable to cellulose solutions
Artikel i vetenskaplig tidskrift, 2020

Molecular interactions governing the recently reported CO2/CO32− chemistry of cellulose/NaOH(aq) solutions are investigated using a cellulose analogue methyl-β-D-glucopyranoside in NaOH(aq) solutions under conditions feasible with cellulose dissolution. 1H, 13C and steady-state heteronuclear Overhauser effect NMR spectroscopy complemented by pH measurements reveal carbohydrate–CO32− interactions as an important component of this chemistry. However, depending on in which order carbohydrate and CO32− are brought together in NaOH(aq) this interaction is different with different implications on stability of the CO32− in the solution.

NaOH(aq)

pH

NMR

Methyl β-D-glucopyranoside

CO 3 2−

CO 2

Cellulose dissolution

Författare

Maria Gunnarsson

Chalmers, Kemi och kemiteknik, Kemiteknik, Skogsindustriell kemiteknik

Diana Bernin

Chalmers, Kemi och kemiteknik, Kemiteknik, Kemisk apparat- och reaktionsteknik

Merima Hasani

Chalmers, Kemi och kemiteknik, Kemiteknik, Skogsindustriell kemiteknik

Wallenberg Wood Science Center (WWSC)

Cellulose

0969-0239 (ISSN)

Vol. 27 2 621-628

Ämneskategorier

Fysikalisk kemi

Annan kemi

Biofysik

DOI

10.1007/s10570-019-02782-6

Mer information

Senast uppdaterat

2021-02-15