The potential of magnetisation transfer NMR to monitor the dissolution process of cellulose in cold alkali
Artikel i vetenskaplig tidskrift, 2019

Cellulose is the most important biopolymer on earth and, when derived from e.g. wood, a promising alternative to for example cotton, which exhibits a large environmental burden. The replacement depends, however, on an efficient dissolution process of cellulose. Cold aqueous alkali systems are attractive but these solvents have peculiarities, which might be overcome by understanding the acting mechanisms. Proposed dissolution mechanisms are for example the breakage of hydrophobic interactions and partly deprotonation of the cellulose hydroxyl groups. Here, we performed a mechanistic study using equimolar aqueous solutions of LiOH, NaOH and KOH to elucidate the dissolution process of microcrystalline cellulose (MCC). The pH was the highest for KOH(aq) followed by NaOH(aq) and LiOH(aq). We used a combination of conventional and advanced solution-state NMR methods to monitor the dissolution process of MCC by solely increasing the temperature from − 10 to 5 °C. KOH(aq) dissolved roughly 25% of the maximum amount of MCC while NaOH(aq) and LiOH(aq) dissolved up to 70%. Water motions on nanoscale timescales present in non-frozen water, remained unaffected on the addition of MCC. Magnetisation transfer (MT) NMR experiments monitored the semi-rigid MCC as a function of temperature. Interestingly, although NaOH(aq) and LiOH(aq) were able to dissolve a similar amount at 5 °C, MT spectra revealed differences with increasing temperature, suggesting a difference in the swollen state of MCC in LiOH(aq) already at − 10 °C. Furthermore, MT NMR shows a great potential to study the water exchange dynamics with the swollen and semi-rigid MCC fraction in these systems, which might give valuable insights into the dissolution mechanism in cold alkali.

Magnetisation transfer

Cellulose

NMR

pH

Dissolution

Alkali

Författare

Maria Gunnarsson

Chalmers, Kemi och kemiteknik, Kemiteknik, Kemisk reaktionsteknik

Merima Hasani

Wallenberg Wood Science Center (WWSC)

Chalmers, Kemi och kemiteknik, Kemiteknik, Kemisk reaktionsteknik

Diana Bernin

Chalmers, Kemi och kemiteknik, Kemiteknik, Kemisk apparatteknik

Cellulose

0969-0239 (ISSN)

Vol. 26 18 9403-9412

Ämneskategorier

Polymerkemi

Fysikalisk kemi

Polymerteknologi

DOI

10.1007/s10570-019-02728-y

Mer information

Senast uppdaterat

2019-12-02