A flexible and free-standing FeS/sulfurized polyacrylonitrile hybrid anode material for high-rate sodium-ion storage
Artikel i vetenskaplig tidskrift, 2019

Sodium-ion based energy storage systems have attracted extensive attention due to the similarities in the mechanism of operation with lithium-ion batteries along with the additional benefit of low cost and high abundance of sodium resources. Iron sulfide-based electrodes that operate via conversion mechanism have shown ample potential for high energy sodium-ion storage. However, the problems related with tremendous volume changes and the dissolution of sodium polysulfides in the electrolyte deteriorate the cycle life and limit their application in sodium-ion batteries (SIBs). Herein, a hybrid anode material, FeS/SPAN-HNF, with iron sulfide (FeS) nanoparticles decorated in a sulfurized polyacrylonitrile (SPAN) fiber matrix is demonstrated as flexible and free-standing anode material for high-rate SIBs. Unlike previous strategies in which FeS is encapsulated in an electrochemically inactive carbon matrix, this study utilizes SPAN, an electrochemically active material, as a dual functional matrix that can efficiently buffer volume expansion and sulfur dissolution of FeS nanoparticles as well as provide significant capacity improvement. The as-designed electrode is self-standing and flexible, without current collectors, binders or additional conductive agents, thus rendering enhanced practical capacity and energy density. This electrode showed a high reversible capacity of 782.8 mAh g−1 at 200 mA g−1 with excellent high rate capability, maintaining 327.5 mAh g−1 after 500 cycles at 5 A g−1, emphasizing promising prospects for the development of flexible and high energy density SIBs.

High energy density

Sulfurized polyacrylonitrile

Iron monosulfide

Self-supporting electrode

Hybrid anode material

Författare

Anupriya K. Haridas

Gyeongsang National University

J. W. Heo

Gyeongsang National University

Xueying Li

Gyeongsang National University

H. J. Ahn

Gyeongsang National University

Xiaohui Zhao

Soochow University

Zhao Deng

Soochow University

Marco Agostini

Chalmers, Fysik, Kondenserade materiens fysik

Aleksandar Matic

Chalmers, Fysik, Kondenserade materiens fysik

J. Ahn

Gyeongsang National University

Chemical Engineering Journal

1385-8947 (ISSN)

Vol. 385 1 April 123453

Ämneskategorier

Kemiteknik

Materialkemi

DOI

10.1016/j.cej.2019.123453

Mer information

Senast uppdaterat

2020-01-09