Structural and Ion Dynamics in Fluorine-Free Oligoether Carboxylate Ionic Liquid-Based Electrolytes
Artikel i vetenskaplig tidskrift, 2020

Here, we investigate the physicochemical and electrochemical properties of fluorine-free ionic liquid (IL)-based electrolytes with two different cations, tetrabutylphosphonium, (P-4,4,4,(4))(+), and tetrabutylammonium, (N-4,N-4,N-4,N-4)(+), coupled to a new anion, 2-[2-(2-methoxyethoxy)ethoxylacetate anion (MEEA), for both neat and (P-4,P-4,P-4,P-4) (MEEA)(-), also doped with 10-40 mol % of Li(MEEA). We find relatively weaker cation-anion interactions in (P-4,P-4,P-4,P-4)(MEEA) than in (N-4,N-4,N-4,N-4)(MEEA), and for both ILs, the structural flexibility of the oligoether functionality in the anion results in low glass transition temperatures, also for the electrolytes made. The pulsed field gradient nuclear magnetic resonance (PFG NMR) data suggest faster diffusion of the (MEEA)(-) anion than (P-4,P-4,P-4,P-4)(+) cation in the neat IL, but the addition of a Li salt results in slightly lower mobility of the former than the latter and lower ionic conductivity. This agrees with the combined Li-7 NMR and attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy data, which unambiguously reveal preferential interactions between the lithium cations and the carboxylate groups of the IL anions, which also increased as a function of the lithium salt concentration. In total, these systems provide a stepping stone for further design of fluorine-free and low glass transition temperature IL-based electrolytes and also stress how crucial it is to control the strength of ion-ion interactions.

Författare

Faiz Ullah Shah

Luleå tekniska universitet

Oleg I. Gnezdilov

Kazan Federal University

Inayat Ali Khan

Luleå tekniska universitet

Andrei Filippov

Kazan State Medical University

Luleå tekniska universitet

Natalia A. Slad

Kazan National Research Technological University

Patrik Johansson

Chalmers, Fysik, Materialfysik

Journal of Physical Chemistry B

1520-6106 (ISSN) 1520-5207 (eISSN)

Vol. 124 43 9690-9700

Ämneskategorier

Oorganisk kemi

Fysikalisk kemi

Materialkemi

DOI

10.1021/acs.jpcb.0c04749

PubMed

33078951

Mer information

Senast uppdaterat

2020-12-11