All-Electrochemical Nanofabrication of Stacked Ternary Metal Sulfide/Graphene Electrodes for High-Performance Alkaline Batteries
Artikel i vetenskaplig tidskrift, 2022
Energy-storage materials can be assembled directly on the electrodes of a battery using electrochemical methods, this allowing sequential deposition, high structural control, and low cost. Here, a two-step approach combining electrophoretic deposition (EPD) and cathodic electrodeposition (CED) is demonstrated to fabricate multilayer hierarchical electrodes of reduced graphene oxide (rGO) and mixed transition metal sulfides (NiCoMnSx). The process is performed directly on conductive electrodes applying a small electric bias to electro-deposit rGO and NiCoMnSx in alternated cycles, yielding an ideal porous network and a continuous path for transport of ions and electrons. A fully rechargeable alkaline battery (RAB) assembled with such electrodes gives maximum energy density of 97.2 Wh kg−1 and maximum power density of 3.1 kW kg−1, calculated on the total mass of active materials, and outstanding cycling stability (retention 72% after 7000 charge/discharge cycles at 10 A g−1). When the total electrode mass of the cell is considered, the authors achieve an unprecedented gravimetric energy density of 68.5 Wh kg−1, sevenfold higher than that of typical commercial supercapacitors, higher than that of Ni/Cd or lead–acid Batteries and similar to Ni–MH Batteries. The approach can be used to assemble multilayer composite structures on arbitrary electrode shapes.
Författare
Jaime Sanchez Sanchez
Chalmers, Industri- och materialvetenskap, Material och tillverkning
Instituto IMDEA Energía
Zhenyuan Xia
Chalmers, Industri- och materialvetenskap, Material och tillverkning
Istituto per la Sintesi Organica e la Fotoreattività (ISOF-CNR)
Nagaraj Patil
Instituto IMDEA Energía
Rebecca Grieco
Instituto IMDEA Energía
Jinhua Sun
Chalmers, Industri- och materialvetenskap, Material och tillverkning
Uta Klement
Chalmers, Industri- och materialvetenskap, Material och tillverkning
Ren Qiu
Chalmers, Fysik, Mikrostrukturfysik
Meganne Christian
Istituto per la Microelettronica e Microsistemi
Fabiola Liscio
Istituto per la Microelettronica e Microsistemi
Vittorio Morandi
Istituto per la Microelettronica e Microsistemi
Rebeca Marcilla
Instituto IMDEA Energía
Vincenzo Palermo
Istituto per la Sintesi Organica e la Fotoreattività (ISOF-CNR)
Chalmers, Industri- och materialvetenskap, Material och tillverkning
Small
1613-6810 (ISSN) 1613-6829 (eISSN)
Vol. 18Grafenkompositer för avancerad behandling av dricksvatten
VINNOVA (2019-05353), 2019-12-02 -- 2022-12-31.
Ämneskategorier
Materialteknik
Kemi
Styrkeområden
Energi
Materialvetenskap
Fundament
Grundläggande vetenskaper
DOI
10.1002/smll.202106403