Alkali emissions characterization in chemical looping combustion of wood, wood char, and straw fuels
Artikel i vetenskaplig tidskrift, 2022

Chemical looping combustion of wood pellets (WP), wood char (WC), and straw pellets (SP) was conducted in a 60 kW CLC pilot with ilmenite and braunite oxygen carriers (OCs). Alkali emissions were investigated with impactor-based and surface ionization detector (SID) measurements. Particle size distributions for WP and WC fuels were dominated by coarse particles formed by refractory species. For SP fuel, the distribution was bimodal with a distinct fine particle mode formed by nucleation of volatile ash species. Thermodynamic modelling of stable alkali species at 800 °C predicted that high KOH(g) and lower concentrations of KCl(g) are stable for WP and WC fuels. For SP fuel, equilibrium K species were dominated by condensed-phase K species, followed by KCl(g), and KOH(g). Modelling of fuel-OC interactions showed that ilmenite decreases equilibrium levels of KOH(g) and KCl(g). Braunite impacted only KOH(g) levels. Impactor sample leachate analysis showed that for WP-braunite operation, the leachate contained KCl, NaCl, KOH, and NaOH, in decreasing order. For WC-ilmenite operation, the samples contained KOH and KCl. For SP fuel, most detected alkalis were KCl. For most cases, speciation of impactor samples qualitatively agreed with modelling predictions. Impactor and SID alkali measurements showed reasonable agreement for WC-braunite and SP-braunite tests.

CO capture 2

Ash chemistry

Biomass conversion

Alkali emissions

Chemical looping combustion

Författare

Ivan Gogolev

Chalmers, Rymd-, geo- och miljövetenskap, Energiteknik

Toni Pikkarainen

Teknologian Tutkimuskeskus (VTT)

Juho Kauppinen

Teknologian Tutkimuskeskus (VTT)

Markus Hurskainen

Teknologian Tutkimuskeskus (VTT)

Anders Lyngfelt

Chalmers, Rymd-, geo- och miljövetenskap, Energiteknik

Fuel Processing Technology

0378-3820 (ISSN)

Vol. 237 107447

Drivkrafter

Hållbar utveckling

Styrkeområden

Energi

Ämneskategorier

Kemiska processer

Bioenergi

Annan materialteknik

DOI

10.1016/j.fuproc.2022.107447

Mer information

Senast uppdaterat

2022-08-29