Membrane Filtration of Lignocellulosic Materials: In situ Monitoring of Membrane Fouling Using Fluid Dynamic Gauging
Doktorsavhandling, 2023
In this work, fluid dynamic gauging (FDG) was employed as an in situ and real-time technique for monitoring the fouling characteristics of microcrystalline cellulose (MCC), Kraft lignin, and steam explosion (STEX) liquors on flat-sheet polymeric membranes. Cross-flow microfiltration (MF) was performed for the MCC and Kraft lignin suspensions, whereas cross-flow ultrafiltration was carried out for the STEX liquors. Furthermore, physical and chemical cleaning were performed to the fouled membranes after the cross-flowMF of MCC and Kraft lignin suspensions, respectively, to restore their separation performance.
The thickness and strength properties of the fouling layers formed were investigated using FDG. The FDG profiles revealed that the build-up of fouling layers was significantly influenced by the feed characteristics and operating conditions. The thickness of the cake layers varied with changes in process conditions, while the cohesive strength of fouling layers increased towards the membrane due to higher compressive pressures exerted on foulants deposited near the surface. Observations from refouling and membrane cleaning also provided significant insights into the fouling behavior,
showing changes in the membrane resistance and flux recovery. These results highlight how FDG can serve as a valuable tool in gaining a better mechanistic understanding of the fouling behavior of streams containing wood components during cross-flow filtration. Such knowledge is essential,
especially in developing membrane separation processes for lignocellulosic materials.
Wood components
Membrane fouling
Fluid dynamic gauging
Cross-flow filtration
Författare
Kenneth Gacutno Arandia
Chalmers, Kemi och kemiteknik, Kemiteknik
Fouling characteristics of microcrystalline cellulose during cross-flow microfiltration: Insights from fluid dynamic gauging and molecular dynamics simulations
Journal of Membrane Science,;Vol. 669(2023)
Artikel i vetenskaplig tidskrift
Monitoring Membrane Fouling Using Fluid Dynamic Gauging: Influence of Feed Characteristics and Operating Conditions
Membranes,;Vol. 13(2023)
Artikel i vetenskaplig tidskrift
Development of a fluid dynamic gauging method for the characterization of fouling behavior during cross-flow filtration of a wood extraction liquor
Food and Bioproducts Processing: Transactions of the Institution of of Chemical Engineers, Part C,;Vol. 128(2021)p. 30-40
Artikel i vetenskaplig tidskrift
Investigation of Kraft lignin fouling and cleaning on regenerated cellulose membranes
However, one of the biggest challenges that limit the separation performance of membrane processes is fouling — the accumulation of contaminants on the surface and within the pores of a membrane. Membrane fouling incurs additional operational costs and opportunity losses due to downtime and cleaning of fouled membranes. Understanding the underlying mechanisms behind membrane fouling through real-time characterization techniques is essential in developing effective control strategies.
This thesis presents fluid dynamic gauging as a real-time technique for monitoring the fouling characteristics of wood components in membrane filtration. The focus is placed on determining the influence of process conditions on the build-up of fouling layers. The findings in this work can serve as a valuable tool in gaining an in-depth understanding of membrane fouling during the separation of wood components, which is an important aspect in developing membrane processes for lignocellulosic materials.
Undersökning av membran-fouling vid tvärflöde filtrering av vedkomponenter
Knut och Alice Wallenbergs Stiftelse, 2014-03-01 -- 2019-02-28.
Knut och Alice Wallenbergs Stiftelse, 2019-04-15 -- 2023-11-15.
Drivkrafter
Hållbar utveckling
Styrkeområden
Produktion
Energi
Ämneskategorier
Pappers-, massa- och fiberteknik
Kemiska processer
Infrastruktur
Chalmers materialanalyslaboratorium
ISBN
978-91-7905-959-0
Doktorsavhandlingar vid Chalmers tekniska högskola. Ny serie: 5425
Utgivare
Chalmers
10:an, Kemigårgen 4, Chalmers
Opponent: Professor Ian Wilson, University of Cambridge, United Kingdom