On metal-organic framework isomers, and the SF6 sorption and fluorescence of an In and a Zr MOF with a tritopic linker
Artikel i vetenskaplig tidskrift, 2025
The concept of framework isomers by network topology analysis is illustrated by a new rod-MOF isomer of In3+ and the tritopic linker 4,4′,4′′-(benzene-1,3,5-triyl-tris(oxy))tribenzoic acid (H3bttb), CTH-41, with a unique 3- and 4-connected net different from 437-MOF. CTH-41 shows affinity for SF6 with a Langmuir area of 1587 m2 g−1 while the new Zr4+ dot-MOF with the same linker [Zr6(bttb)4(O)4(OH)4] CTH-42, forms the 3-, 12-connected llj-net based on a different conformation of the flexible bttb linker.
Författare
Hao Li
Chalmers, Kemi och kemiteknik, Kemi och biokemi
Francoise Mystere Amombo Noa
Catholic University of Central Africa
Chalmers, Kemi och kemiteknik, Kemi och biokemi
Michelle Åhlén
Uppsala universitet
Zhejian Cao
Chalmers, Life sciences, Systembiologi
Joakim Andreasson
Chalmers, Kemi och kemiteknik, Kemi och biokemi
Ocean Cheung
Uppsala universitet
Lars Öhrström
Chalmers, Kemi och kemiteknik
Chemical Communications
1359-7345 (ISSN) 1364-548X (eISSN)
Vol. 61 14129-14132Ämneskategorier (SSIF 2025)
Oorganisk kemi
Infrastruktur
Chalmers materialanalyslaboratorium
DOI
10.1039/d5cc02180d
PubMed
40827581