Modulation and binding properties of extended glycoluril molecular clips
Artikel i vetenskaplig tidskrift, 2008

A glycoluril clip (1) provides a deep cavity for binding of guest molecules. Guest species interact preferentially via hydrogen bonding or ion–lone pair interactions. Complexation-induced conformational modulation of the cavity wall distance was observed. At higher guest–host ratios, inclusion compounds with organic guest molecules are obtained. The X-ray crystallographic structure of 1.(NH4PF6).3CHCl3.2CH3OH shows formation of a network of clips connected via polar and non-polar interactions.

X-ray analysis

host-guest system

NMR

Författare

Prasad Polavarapu

Uppsala universitet

Helena Melander

Uppsala universitet

Vratislav Langer

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

Adolf Gogoll

Uppsala universitet

Helena Grennberg

Uppsala universitet

New Journal of Chemistry

1144-0546 (ISSN) 1369-9261 (eISSN)

Vol. 32 4 643-651

Ämneskategorier

Kemi

Organisk kemi

DOI

10.1039/b715208f