Structure and magnetic properties of a trinuclear nickel(II) complex with benzenetricarboxylate bridge
Artikel i vetenskaplig tidskrift, 2008

Novel trinuclear Ni(II) complex [Ni3(pmdien)3(btc)(H2O)3](ClO4)3·4H2O, 1 where pmdien = N,N,N′,N′,N″-pentamethyldiethylenetriamine, H3btc = 1,3,5-benzenetricarboxylic (trimesic) acid, has been prepared and structurally characterized. Three nickel atoms are bridged by btc trianion and their coordination sphere is completed by three N atoms of pmdien and O atom of the water molecule. The three nickel(II) magnetic centers are equivalent and their coordination spheres are completed to deformed octahedrons. Magnetic susceptibility was measured over the temperature range 1.8–300 K and zJ′ = −0.19 cm−1, D = 3.79 cm−1, g = 2.18 parameters were calculated.

crystal structure

trimesic acid

Nickel complex

trinuclear complexes




Jerzy Mrozinski

University of Wroclaw

Alina Bienko

University of Wroclaw

Pavel Kopel

AVX Czech Republic

Vratislav Langer

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

Inorganica Chimica Acta

0020-1693 (ISSN)

Vol. 361 12-13 3723-3729


Organisk kemi

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