Anions for lithium battery electrolytes: A spectroscopic and theoretical study of the B(CN)4- anion of the ionic liquid C2mim[B(CN)4]
Artikel i vetenskaplig tidskrift, 2008

On the basis of computations, the B(CN)4 - (bison) anion is shown to be of interest as a fluorine-free alternative in lithium-conducting electrolytes. Compared to PF6 - the bison anion has an equally high stability toward oxidation, while at the same time offering a large reduction of the lithium-ion pair dissociation energy. The bison anion is readily available in a number of ambient-temperature ionic liquids (ILs). In this work, the Raman spectrum of the IL C2mim [B(CN)4] reveals an almost unperturbed bison anion and, consequently, the effects of the anion on the Raman shifts of C2mim + are also very small. © 2008 The Electrochemical Society.

Författare

Johan Scheers

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Patrik Johansson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Per Jacobsson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Journal of the Electrochemical Society

0013-4651 (ISSN)

Vol. 155 9 A628-A634

Ämneskategorier

Annan teknik

Fysik

Den kondenserade materiens fysik

DOI

10.1149/1.2943214

Mer information

Skapat

2017-10-08