A (10,3)-b net by sulfate hydrogen-bonded biimidazolate complexes
Artikel i vetenskaplig tidskrift, 2003

The synthesis and crystal structure of Delta-[Cr(Hbiim)(H(2)biim)(2)]SO4.H2O (H(2)biim = biimidazole) are presented. A network is formed by sligthly distorted Delta-[Cr( Hbiim)(H(2)biim)(2)](2+) octahedra triple bridged by sulfate anions to give a (10,3)-b net. The final structure is given by three such interpenetrating nets, all with the same chirality on chromium. It is shown that the same net and interpenetration occur in [Fe(H(2)biim)(3)]CO3.MeOH.

porous materials

chemistry

tool

coordination polymers

metal-complexes

Författare

Krister Larsson

Chalmers, Institutionen för material- och ytkemi, Oorganisk kemi

Lars Öhrström

Chalmers, Institutionen för material- och ytkemi, Oorganisk kemi

Crystengcomm

Vol. 5 222-225

Ämneskategorier

Kemi