Crucial influence of solvent and chirality - The formation of helices and three-dimensional nets by hydrogen-bonded biimidazolate complexes

Lars Öhrström; Krister Larsson; Stefan Borg; Stefan Norberg

Crucial influence of solvent and chirality - The formation of helices and three-dimensional nets by hydrogen-bonded biimidazolate complexes
Artikel i vetenskaplig tidskrift, 2001

Deprotonation and recrystallisation of racemic [Co(2,2'-biimidazole)(3)]- [NO3](3) by ammonia in water/dimethylformamide solutions gave crystals of [Co(Hbiim)(3)].0.8H(2)O .0.5DMF (2: Hbiim=monoanion of 2,2'-biimidazole, DMF = dimethylformamide), a porous material that contains fourfold interpenetrating (10,3) three-dimensional nets formed by neutral, hydrogen-bonded [Co(Hbiim)(3)] units, with DMF molecules in the narrow channels. Recrystallisation of [Delta -Co(2,2'-biimidazolate)(3)] gave helices instead of the expected (10,3)-a net. These results are discussed in the light of additional density functional theory and molecular mechanics calculations and the X-ray structure of [Co(H(2)biim)(3)][NO3](3).

N Ligands

Hydrogen Bonds

Zeolite Analogs

Network

Crystal Engineering

Magnets

Coordination Polymers

Supramolecular Chemistry

Design

Crystal Structure

Metal-organic Frameworks

Cobalt

Författare

Lars Öhrström

Institutionen för oorganisk kemi

Forskning Andra publikationer

Krister Larsson

Oorganisk kemi

Forskning Andra publikationer

Stefan Borg

Institutionen för oorganisk kemi

Forskning Andra publikationer

Stefan Norberg

Institutionen för oorganisk kemi

Forskning Andra publikationer

Chemistry - A European Journal

0947-6539 (ISSN) 1521-3765 (eISSN)

Vol. 7 22 4805-4810

Ämneskategorier

Oorganisk kemi

Mer information

Senast uppdaterat

2024-08-26

Crucial influence of solvent and chirality - The formation of helices and three-dimensional nets by hydrogen-bonded biimidazolate complexes Artikel i vetenskaplig tidskrift, 2001

Författare

Lars Öhrström

Krister Larsson

Stefan Borg

Stefan Norberg

Chemistry - A European Journal

Ämneskategorier

Mer information

Senast uppdaterat

Crucial influence of solvent and chirality - The formation of helices and three-dimensional nets by hydrogen-bonded biimidazolate complexes
Artikel i vetenskaplig tidskrift, 2001