Entropy-enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data
Artikel i vetenskaplig tidskrift, 2012
Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors.
sequence specificity
thermodynamics
phantom
binding
derivatives
anthracene
calorimetry
pyrene
dna
Författare
Evgeni B. Starikov
Chalmers, Kemi- och bioteknik, Fysikalisk kemi
Bengt Nordén
Chalmers, Kemi- och bioteknik, Fysikalisk kemi
Chemical Physics Letters
0009-2614 (ISSN)
Vol. 538 118-120Styrkeområden
Nanovetenskap och nanoteknik
Energi
Livsvetenskaper och teknik (2010-2018)
Materialvetenskap
Ämneskategorier
Fysikalisk kemi
DOI
10.1016/j.cplett.2012.04.028