An inter-penetrating primitive cubic net formed by hydrogen bonds and coordination bonds in catena-poly[[bis-(methanol-κO)bis-(thio-cyanato- κN)iron(II)] -μ 1,2-bis(4-pyridyl-methylene)hydrazine- κ2 N:N′]
Artikel i vetenskaplig tidskrift, 2008

In the title compound, [Fe(NCS)2(C12H10N4)(CH4O)2] n , at 153 (2) K, the Fe atom is located on an inversion centre, as is the centre of the N - N bond in the ligand mol-ecule. The structure contains a one-dimensional coordination polymer with an Fe⋯Fe distance of 15.866 (7) Å and can be described as two inter-penetrating six-connected primitive cubic (pcu) three-dimensional networks when additional inter-molecular O - H⋯S hydrogen bonds are taken into account. The compound is not isostructural with the corresponding Mn II compound as they differ in the rotation around the M - O bond by 90°, giving rise to completely different hydrogen-bond patterns. This study demonstrates the impact of conformational differences on the final supramolecular arrangement.


Lars Öhrström

Fysikalisk kemi

Vratislav Langer

Oorganisk miljökemi 1

Mohamed I D M Ghazzali

Acta Crystallographica Section C: Crystal Structure Communications

0108-2701 (ISSN) 1600-5759 (eISSN)

Vol. 64 8


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