Reversible sorption in the crystalline microporous semiconductor Rb-CTH-1
Artikel i vetenskaplig tidskrift, 2010

The sorption capacity of the recently reported crystalline microporous semiconductor Rb-CTH-1 was investigated, revealing that the structure demonstrates heat-induced reversible sorption of 3 wt% water and hydrocarbons. The Rb-CTH-1 structure maintains its crystallinity and semiconducting properties when heated to 150 degrees C. The treatment causes desorption induced irreversible rearrangements of the remaining guest species with a response in the semiconductive properties of the material. (C) 2010 Elsevier Inc. All rights reserved.

Microporous semiconductor

IR spectroscopy

Host-guest system

Sorption

nh3

k-sbc-1

h-zsm-5

reduction

water

zeolites

nox

X-ray diffraction

Författare

Alexander Shulman

Chalmers University of Technology

Ezio Zanghellini

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Anders Palmqvist

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

Journal of Solid State Chemistry

0022-4596 (ISSN) 1095-726X (eISSN)

Vol. 183 1912-1916

Ämneskategorier

Kemiteknik

DOI

10.1016/j.jssc.2010.06.012