Methane oxidation over Pd supported on ceria–alumina under rich/lean cycling conditions
Artikel i vetenskaplig tidskrift, 2013
Catalysts with highly dispersed palladium on alumina, alumina doped with 20 wt% ceria and ceria have been prepared, characterized and examined for net-lean methane oxidation. In particular, the activity and selectivity were investigated during rich/lean cycling of the feed. The ceria content is found to influence both the general and the instantaneous activity responses. The results indicate that the active phase of palladium changes between reduced and oxidised Pd during the rich/lean cycling, and that the process is influenced by the presence of ceria.
Selectivity
Environmental catalysis
Low-temperature activity
PdO
CH4 activation
Författare
Sheedeh Fouladvand
Chalmers, Kemi- och bioteknik, Teknisk ytkemi
Kompetenscentrum katalys
Stefan Schernich
Friedrich-Alexander-Universität Erlangen Nurnberg (FAU)
Jörg Libuda
Friedrich-Alexander-Universität Erlangen Nurnberg (FAU)
Henrik Grönbeck
Kompetenscentrum katalys
Chalmers, Teknisk fysik, Kemisk fysik
Torben Pingel
Kompetenscentrum katalys
Chalmers, Teknisk fysik, Eva Olsson Group
Eva Olsson
Chalmers, Teknisk fysik, Eva Olsson Group
Kompetenscentrum katalys
Magnus Skoglundh
Kompetenscentrum katalys
Chalmers, Kemi- och bioteknik, Teknisk ytkemi
Per-Anders Carlsson
Chalmers, Kemi- och bioteknik, Teknisk ytkemi
Kompetenscentrum katalys
Topics in Catalysis
1022-5528 (ISSN) 1572-9028 (eISSN)
Vol. 56 1-8 410-415Katalysatorer för krävande miljöer
Stiftelsen för Strategisk forskning (SSF) (RMA08-0085), 2009-07-01 -- 2013-06-30.
Drivkrafter
Hållbar utveckling
Styrkeområden
Nanovetenskap och nanoteknik
Transport
Energi
Materialvetenskap
Ämneskategorier
Kemiska processer
Fundament
Grundläggande vetenskaper
Infrastruktur
Chalmers materialanalyslaboratorium
DOI
10.1007/s11244-013-9988-2