The effect of rosin acid on hydrodeoxygenation of fatty acid
Artikel i vetenskaplig tidskrift, 2019

In this study, inhibition of tall oil fatty acid hydrodeoxygenation (HDO) activity due to addition of rosin acid over sulfided NiMo/Al2O3 was investigated. Oleic acid and abietic acid were used as model compounds for fatty acid and rosin acid respectively in tall oil. After completion of each HDO experiment, the NiMo catalysts were recovered and used again under the same conditions. The results showed that the oleic acid HDO activity of sulfided catalysts was inhibited by addition of abietic acid due to competitive adsorption and increased coke deposition. The rate of carbon deposition on the catalysts increased when abietic acid was added to oleic acid feed. Moreover, the coke was in a more advanced form with higher stability for the catalysts exposed to both oleic acid and abietic acid. Furthermore, a clear correlation between the rate of coke formation and concentration of abietic acid was observed.

Inhibition

Carbon deposition

Rosin acid

Hydrodeoxygenation (HDO)

Coke formation

Författare

Houman Ojagh

Chalmers, Kemi och kemiteknik, Kemiteknik

Kompetenscentrum katalys (KCK)

Derek Creaser

Chalmers, Kemi och kemiteknik, Kemiteknik

Kompetenscentrum katalys (KCK)

Muhammad Abdus Salam

Chalmers, Kemi och kemiteknik, Kemiteknik

Kompetenscentrum katalys (KCK)

Eva Lind Grennfelt

Preem

Louise Olsson

Chalmers, Kemi och kemiteknik, Kemiteknik

Kompetenscentrum katalys (KCK)

Journal of Energy Chemistry

2095-4956 (ISSN)

Vol. 28 85-94

Kompetenscentrum katalys, KCK

Scania CV AB, 2018-01-01 -- 2021-12-31.

Volvo Car Corporation, 2018-01-01 -- 2021-12-31.

Chalmers, 2018-01-01 -- 2021-12-31.

Preem, 2018-01-01 -- 2021-12-31.

Johnson Matthey AB, 2018-01-01 -- 2021-12-31.

Energimyndigheten, 2018-01-01 -- 2021-12-31.

Volvo Group, 2018-01-01 -- 2021-12-31.

ECAPS AB, 2018-01-01 -- 2021-12-31.

Umicore AG & Co KG, 2018-01-01 -- 2021-12-31.

Styrkeområden

Energi

Ämneskategorier

Annan kemiteknik

Annan kemi

Organisk kemi

DOI

10.1016/j.jechem.2018.01.023

Mer information

Senast uppdaterat

2019-03-03