Synthesis and ligand substitution reactions of κ4-B,S,S',S''-ruthenaboratranes
Artikel i vetenskaplig tidskrift, 2019

A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S',S''-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S',S''-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].

Författare

Mark Foreman

Chalmers, Kemi och kemiteknik, Energi och material, Kärnkemi

Anthony F. Hill

Australian National University

Chenxi Ma

Australian National University

Never Tshabang

Australian National University

University of Botswana

Andrew J.P. White

Imperial College London

Dalton Transactions

1477-9226 (ISSN) 1477-9234 (eISSN)

Vol. 48 1 209-219

Ämneskategorier

Oorganisk kemi

Teoretisk kemi

Organisk kemi

DOI

10.1039/c8dt04278k

PubMed

30516190

Mer information

Senast uppdaterat

2019-01-08