Synthesis and ligand substitution reactions of κ4-B,S,S',S''-ruthenaboratranes
Artikel i vetenskaplig tidskrift, 2019
A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S',S''-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S',S''-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].
Författare
Mark Foreman
Chalmers, Kemi och kemiteknik, Energi och material
Anthony F. Hill
Australian National University
Chenxi Ma
Australian National University
Never Tshabang
Australian National University
University of Botswana
Andrew J.P. White
Imperial College London
Dalton Transactions
1477-9226 (ISSN) 1477-9234 (eISSN)
Vol. 48 1 209-219Ämneskategorier
Oorganisk kemi
Teoretisk kemi
Organisk kemi
DOI
10.1039/c8dt04278k
PubMed
30516190