Toughening of a Soft Polar Polythiophene through Copolymerization with Hard Urethane Segments
Artikel i vetenskaplig tidskrift, 2021
Polar polythiophenes with oligoethylene glycol side chains are exceedingly soft materials. A low glass transition temperature and low degree of crystallinity prevents their use as a bulk material. The synthesis of a copolymer comprising 1) soft polythiophene blocks with tetraethylene glycol side chains, and 2) hard urethane segments is reported. The molecular design is contrary to that of other semiconductor-insulator copolymers, which typically combine a soft nonconjugated spacer with hard conjugated segments. Copolymerization of polar polythiophenes and urethane segments results in a ductile material that can be used as a free-standing solid. The copolymer displays a storage modulus of 25 MPa at room temperature, elongation at break of 95%, and a reduced degree of swelling due to hydrogen bonding. Both chemical doping and electrochemical oxidation reveal that the introduction of urethane segments does not unduly reduce the hole charge-carrier mobility and ability to take up charge. Further, stable operation is observed when the copolymer is used as the active layer of organic electrochemical transistors.
organic electrochemical transistors (OECT)
polar conjugated polymers
swelling
chemical and electrochemical doping
urethane
Författare
Sepideh Zokaei
Chalmers, Kemi och kemiteknik, Tillämpad kemi
Renee Kroon
Chalmers, Kemi och kemiteknik, Tillämpad kemi
Johannes Gladisch
Wallenberg Wood Science Center (WWSC)
Linköpings universitet
Bryan D. Paulsen
Northwestern University
Wonil Sohn
Northwestern University
Anna Hofmann
Chalmers, Kemi och kemiteknik, Tillämpad kemi
Gustav Persson
Chalmers, Fysik, Nano- och biofysik
Arne Stamm
Kungliga Tekniska Högskolan (KTH)
Per Olof Syrén
Wallenberg Wood Science Center (WWSC)
Kungliga Tekniska Högskolan (KTH)
Eva Olsson
Chalmers, Fysik, Nano- och biofysik
Jonathan Rivnay
Northwestern University
Eleni Stavrinidou
Linköpings universitet
Wallenberg Wood Science Center (WWSC)
Anja Lund
Chalmers, Kemi och kemiteknik, Tillämpad kemi
Christian Müller
Wallenberg Wood Science Center (WWSC)
Chalmers, Kemi och kemiteknik, Tillämpad kemi
Advanced Science
2198-3844 (ISSN) 21983844 (eISSN)
Vol. 8 2 2002778Ämneskategorier (SSIF 2011)
Polymerkemi
Oorganisk kemi
Materialkemi
Infrastruktur
Chalmers materialanalyslaboratorium
DOI
10.1002/advs.202002778