Ion Dynamics and Nanostructures of Diluted Ionic Liquid Electrolytes
Artikel i vetenskaplig tidskrift, 2022

Diluted ionic liquid electrolytes are promising candidates in next-generation batteries enabling the implementation of lithium metal anodes. The diluent should fully mix with the ionic liquid while not interacting with the Li ions to preserve the ionic liquid character, which is beneficial for Li-metal electrode stability. We report on the influence of a hydrofluoroether (HFE) diluent on ion dynamics and nanostructure of an ionic liquid electrolyte. We show that the ionic liquid and the diluent are fully miscible and that the solvation structure of the Li ions is not affected by the presence of HFE. The increase in the conductivity by the addition of the diluent is directly related to a decrease in viscosity with faster dynamics of all ionic species. However, the relative increase in mobility is considerably larger for the ionic liquid cation as a result of a preferred interaction with HFE. On the microscopic scale, more complex local non-Gaussian diffusive dynamics are found, faster than what is expected from the self-diffusion coefficient. The relative change of the dynamics with the addition of HFE on macro- and microscopic length scales correlates well, which underlines the connection between the motions probed on different length and time scales.

Författare

Filippa Lundin

Chalmers, Fysik, Materialfysik

Alexander Idström

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Peter Falus

Institut Laue-Langevin

Lars Evenäs

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Shizhao Xiong

Chalmers, Fysik, Materialfysik

Aleksandar Matic

Chalmers, Fysik, Materialfysik

Journal of Physical Chemistry C

1932-7447 (ISSN) 1932-7455 (eISSN)

Vol. 126 38 16262-16271

Ämneskategorier

Oorganisk kemi

Fysikalisk kemi

Annan kemi

DOI

10.1021/acs.jpcc.2c04503

Mer information

Senast uppdaterat

2023-10-26