Fullerene Nucleating Agents: A Route Towards Thermally Stable Photovoltaic Blends
Artikel i vetenskaplig tidskrift, 2014
The bulk-heterojunction nanostructure of non-crystalline polymer: fullerene blends has the tendency to rapidly coarsen when heated above its glass transition temperature, which represents an important degradation mechanism. We demonstrate that fullerene nucleating agents can be used to thermally arrest the nanostructure of photovoltaic blends that comprise a non-crystalline thiophene-quinoxaline copolymer and the widely used fullerene derivative [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM). To this end, C-60 fullerene is employed to efficiently nucleate PCBM crystallization. Sub-micrometer-sized fullerene crystals are formed when as little as 2 wt% C-60 with respect to PCBM is added to the blend. These reach an average size of only 200 nanometers upon introduction of more than 8 wt% C-60. Solar cells based on C-60-nucleated blends indicate significantly improved thermal stability of the bulk-heterojunction nanostructure even after annealing at an elevated temperature of 130 degrees C, which lies above the glass transition temperature of the blend. Moreover, we find that various other compounds, including C-70 fullerene, single-walled carbon nanotubes, and sodium benzoate, as well as a number of commercial nucleating agents-commonly used to clarify isotactic polypropylene-permit to control crystallization of the fullerene phase.
Författare
Camilla Lindqvist
Chalmers, Kemi- och bioteknik, Polymerteknologi
J. Bergqvist
Linköpings universitet
Ching-Chiao Feng
Chalmers, Kemi- och bioteknik, Polymerteknologi
Stefan Gustafsson
SuMo Biomaterials
Chalmers, Teknisk fysik, Eva Olsson Group
Olof Bäcke
Chalmers, Teknisk fysik, Eva Olsson Group
N. D. Treat
Imperial College London
C. Bounioux
Ben-Gurion University of the Negev
Patrik Henriksson
Chalmers, Kemi- och bioteknik, Polymerteknologi
Renee Kroon
Chalmers, Kemi- och bioteknik, Polymerteknologi
Ergang Wang
Chalmers, Kemi- och bioteknik, Polymerteknologi
Anke Sanz-Velasco
Chalmers, Teknisk fysik, Elektronikmaterial
Per Magnus Kristiansen
Fachhochschule Nordwestschweiz
N. Stingelin
Imperial College London
Eva Olsson
Chalmers, Teknisk fysik, Eva Olsson Group
Olle Inganaes
Linköpings universitet
Mats Andersson
Chalmers, Kemi- och bioteknik, Polymerteknologi
Christian Müller
Chalmers, Kemi- och bioteknik, Polymerteknologi
Advanced Energy Materials
1614-6832 (ISSN) 1614-6840 (eISSN)
Vol. 4 9 1301437- 1301437Styrkeområden
Nanovetenskap och nanoteknik
Energi
Materialvetenskap
Ämneskategorier (SSIF 2011)
Materialteknik
Energiteknik
Fysik
Kemi
DOI
10.1002/aenm.201301437