Alloy Plasmonics - Fundamentals and Application in Catalysis
Licentiatavhandling, 2020

Alloys have for a long time been important in the development of our society; from the bronze age, where man learned how to alloy copper with tin, to today, where many products are made of steel and aluminum alloys. Similarly, but maybe not as generally well known, also in heterogeneous catalysis alloys are explored to develop solutions to increase activity and selectivity of chemical processes. Furthermore, alloys have lately been proposed as a new paradigm in nanophotonics, as a means to tailor optical properties of nanomaterials that find applications within telecommunication, sensing, or biotechnology. Nanophotonics and catalysis, separately and in combination, are the focus of this thesis. Specifically, we have compiled a library of alloy complex dielectric functions for the late transition metals by utilizing time-dependent density-functional theory. The calculated dielectric functions were benchmarked by (i) nanofabricating series of alloy nanoparticle arrays with systematically varying composition, (ii) measuring their plasmonic properties, and (iii) comparing these properties with electrodynamic simulations of alloy nanoparticles, using the dielectric function library as the input. The second theme in this thesis is plasmon-enhanced catalysis. In this field there is a continuous discussion regarding the reaction enhancing mechanisms when noble metal catalyst nanoparticles are irradiated with visible light during a catalytic reaction. Here we investigated the role of photothermal enhancement of reactions by tailoring the catalytic activity of nanofabricated particles without radiation by means of alloying Pd with Au, while keeping the optical absorption cross-section constant, as confirmed by electrodynamics simulations using our dielectric function library as the input.

CO oxidation



heterogeneous catalysis





dielectric function


Opponent: Alexander Friemann Dmitriev, Institutionen för Fysik, Göteborgs Universitet


Christopher Tiburski

Chalmers, Fysik, Kemisk fysik

A Library of Late Transition Metal Alloy Dielectric Functions for Nanophotonic Applications

Advanced Functional Materials,; Vol. 30(2020)

Artikel i vetenskaplig tidskrift

C. Tiburski, S, Nilsson, Z. Say, J. Fritzsche, C. Langhammer, Light-Off in Plasmon-Mediated Photocatalysis.

Wallenberg Academy Fellow 2016

Knut och Alice Wallenbergs Stiftelse (KAW2016.0210), 2017-07-01 -- 2022-06-30.


Nanovetenskap och nanoteknik








Opponent: Alexander Friemann Dmitriev, Institutionen för Fysik, Göteborgs Universitet

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