Determination of Fe2+ and Fe3+ in aqueous solutions containing food chelators by differential pulse anodic stripping voltammetry
Journal article, 2010

The objective was to investigate interactions between iron and food chelators in an aqueous environment. The net complexation were investigated by DPASV in a NaClO4 electrolyte using a platinum electrode. The experimental conditions were simulating the environment of the human duodenum. The results indicated a net coordination affinity between Fe2+ and the organic acids in the following order; ascorbic acidphytate>pyruvate>lactate>acetate. For Fe3+ net complexation, the stability was in the order of lactate>phytate>pyruvate>acetate>citrate. In conclusion, DPASV in conjunction with a platinum electrode is suitable for studies in aqueous systems where the net complexation of metal is important.

Fe2+

organic acids

ascorbic acid

Fe3+

voltammetry

Author

Nathalie Scheers

Chalmers, Chemical and Biological Engineering, Life Sciences

Thomas Andlid

Chalmers, Chemical and Biological Engineering, Life Sciences

Marie Alminger

Chalmers, Chemical and Biological Engineering, Life Sciences

Ann-Sofie Sandberg

Chalmers, Chemical and Biological Engineering, Life Sciences

Electroanalysis

1040-0397 (ISSN) 1521-4109 (eISSN)

Vol. 22 10 1090-1096

Subject Categories

Inorganic Chemistry

Areas of Advance

Life Science Engineering (2010-2018)

DOI

10.1002/elan.200900533

More information

Created

10/7/2017