A Comparison of Americium Extractions as a Function of Time using Two Bis-Triazine-Bipyridine Ligands in Long-Chained Alcohol Diluents
Artikel i vetenskaplig tidskrift, 2014

The rate of americium mass transfer between the aqueous and organic phase in a solvent extraction system has been investigated. The ligand used is CyMe4-BTBP and the diluents are long-chained alcohols. The results are compared with earlier reported data using C5-BTBP as ligand. In the C5-BTBP system the rate of the extraction could be correlated with the interfacial tension of the system, while not in the CyMe4-BTBP system. In the CyMe4-BTBP system a high (> 12) or low (< 9) dielectric constant of the diluent affects the equilibrium distribution ratio. Dielectric constants in between these two did not affect the extraction.

interfacial tension

Solvent extraction

ligand side group effects

rate of extraction

Författare

Elin Löfström Engdahl

Chalmers, Kemi- och bioteknik, Kärnkemi

Emma Aneheim

Chalmers, Kemi- och bioteknik, Kärnkemi

Mark Foreman

Chalmers, Kemi- och bioteknik, Kärnkemi

Christian Ekberg

Chalmers, Kemi- och bioteknik, Kärnkemi

Gunnar Skarnemark

Chalmers, Kemi- och bioteknik, Kärnkemi

Separation Science and Technology

0149-6395 (ISSN) 1520-5754 (eISSN)

Vol. 49 13 2060-2065

Ämneskategorier

Annan kemi

Kemi

DOI

10.1080/01496395.2014.911325