Fast charging negative electrodes based on anatase titanium dioxide beads for highly stable Li-ion capacitors
Artikel i vetenskaplig tidskrift, 2020

Hybrid energy storage systems aim to achieve both high power and energy densities by combining supercapacitor-type and battery-type electrodes in tandem. The challenge is to find sustainable materials as fast charging negative electrodes, which are characterized by high capacity retention. In this study, mesoporous anatase beads are synthetized with tailored morphology to exploit fast surface redox reactions. The TiO2-based electrodes are properly paired with a commercial activated carbon cathode to form a Li-ion capacitor. The titania electrode exhibits high capacity and rate performance. The device shows extremely stable performance with an energy density of 27 mWh g-1 at a specific current of 2.5 A g−1 for 10,000 cycles. The remarkable stability is associated with a gradual shift of the potential during cycling as result of the formation of cubic LiTiO2 on the surface of the beads. This phenomenon renews the interest in using TiO2 as negative electrode for Li-ion capacitors.

Hybrid asymmetric supercapacitor

Hybrid energy storage system

Activated carbon

Li-ion battery anode

Titanium dioxide anatase mesoporous anode


Giulio Calcagno

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Antiope Lotsari

Chalmers, Kemi och kemiteknik, Tillämpad kemi

A. Dang

University of California

Simon Lindberg

Chalmers, Fysik, Subatomär fysik och plasmafysik

Anders Palmqvist

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Aleksandar Matic

Chalmers, Fysik, Materialfysik

Carmen Cavallo

Chalmers, Fysik, Materialfysik

Materials Today Energy

24686069 (eISSN)

Vol. 16 100424

Energi OCH Effekt: Hybridsuperkondensatorer

Energimyndigheten (39045-1), 2015-01-01 -- 2018-12-31.


Oorganisk kemi


Annan kemiteknik

Annan fysik



Mer information

Senast uppdaterat